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What is the standard enthalpy of formation of carbon dioxide (CO2) from its elements at standard conditions if the standard enthalpy of formation of carbon (C) and oxygen (O2) are -94.05 kJ/mol and 0 kJ/mol, respectively?

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The standard enthalpy of formation of a compound is the change in enthalpy when one mole of the compound is formed from its elements in their standard states. In this case, we want to find the standard enthalpy of formation of carbon dioxide  CO2  from its elements, carbon  C  and oxygen  O2 .The balanced chemical equation for the formation of CO2 is:C  graphite  + O2  g   CO2  g The standard enthalpy of formation of carbon  C  in its standard state  graphite  is given as -94.05 kJ/mol, and the standard enthalpy of formation of oxygen  O2  in its standard state  gas  is given as 0 kJ/mol.However, the given enthalpy of formation for carbon  -94.05 kJ/mol  is incorrect. The standard enthalpy of formation for an element in its standard state is always 0 kJ/mol. Therefore, the correct standard enthalpy of formation for carbon  C  in its standard state  graphite  should be 0 kJ/mol.Now, we can use the following equation to find the standard enthalpy of formation of CO2:Hf CO2  = [Hf CO2  - Hf C  - Hf O2 ]Since the standard enthalpy of formation for both carbon and oxygen in their standard states is 0 kJ/mol, the equation simplifies to:Hf CO2  = Hf CO2 The standard enthalpy of formation of CO2 is -393.5 kJ/mol.

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