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How does an increase in the concentration of reaction products affect the rate of the reaction between hydrogen peroxide and potassium iodide, and what is the underlying mechanism behind this effect?

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An increase in the concentration of reaction products can affect the rate of the reaction between hydrogen peroxide  H2O2  and potassium iodide  KI  according to Le Chatelier's principle. This principle states that if a system at equilibrium is subjected to a change in concentration, temperature, or pressure, the system will adjust itself to counteract the change and restore a new equilibrium.The reaction between hydrogen peroxide and potassium iodide can be represented as follows:H2O2  aq  + 2 KI  aq   2 H2O  l  + 2 KI  aq  + I2  s In this reaction, hydrogen peroxide reacts with potassium iodide to produce water, potassium iodide, and iodine. When the concentration of the reaction products  H2O, KI, and I2  increases, the system will try to counteract this change by shifting the equilibrium position to favor the reverse reaction, which consumes the products and forms more reactants  H2O2 and KI .This shift in equilibrium will result in a decrease in the rate of the forward reaction  the reaction between H2O2 and KI , as the system tries to restore equilibrium by consuming the excess products. Consequently, the rate of the reaction between hydrogen peroxide and potassium iodide will decrease when the concentration of the reaction products increases.The underlying mechanism behind this effect is related to the collision theory, which states that the rate of a reaction depends on the frequency and energy of collisions between reactant molecules. When the concentration of reaction products increases, the frequency of collisions between the reactant molecules  H2O2 and KI  decreases, as there are fewer reactant molecules available for collisions. This leads to a decrease in the rate of the reaction.
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