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Calculate the formal charge of each atom in the molecule SO3.

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To calculate the formal charge of each atom in SO3, we need to follow these steps:1. Determine the number of valence electrons for each atom.2. Calculate the number of electrons each atom would have in a completely covalent bond.3. Subtract the number of electrons assigned to each atom in step 2 from the number of valence electrons in step 1.Sulfur  S  is in group 16, so it has 6 valence electrons.Oxygen  O  is also in group 16, so it also has 6 valence electrons.SO3 has a double bond between the central sulfur atom and one of the oxygen atoms, and single bonds with the other two oxygen atoms. For the sulfur atom:- It forms a double bond with one oxygen atom, so it shares 4 electrons  2 from each atom .- It forms single bonds with the other two oxygen atoms, so it shares 2 electrons with each  1 from each atom .- In total, sulfur shares 8 electrons in the molecule.For the oxygen atom with a double bond:- It shares 4 electrons with the sulfur atom  2 from each atom .- It has 2 lone pairs, which means it has 4 non-bonding electrons.- In total, this oxygen atom has 8 electrons assigned to it.For the two oxygen atoms with single bonds:- Each shares 2 electrons with the sulfur atom  1 from each atom .- Each has 3 lone pairs, which means each has 6 non-bonding electrons.- In total, each of these oxygen atoms has 8 electrons assigned to them.Now, we can calculate the formal charge for each atom:Formal charge of S = Valence electrons - Assigned electrons = 6 - 8 = -2Formal charge of O  double bond  = Valence electrons - Assigned electrons = 6 - 8 = -2Formal charge of O  single bond  = Valence electrons - Assigned electrons = 6 - 8 = -2However, this calculation seems to be incorrect, as the sum of the formal charges should equal the overall charge of the molecule, which is neutral for SO3. Let's reevaluate the bonding situation in SO3.In reality, SO3 has resonance structures, meaning that the double bond is distributed equally among the three oxygen atoms. This means that each S-O bond is essentially 1.33 bonds  4/3 , not a true double bond or single bond.Let's recalculate the formal charges considering the resonance structures:For the sulfur atom:- It shares 4 electrons with each oxygen atom  4/3 from each atom .- In total, sulfur shares 12 electrons in the molecule.For each oxygen atom:- Each shares 4 electrons with the sulfur atom  4/3 from each atom .- Each has 2 lone pairs, which means it has 4 non-bonding electrons.- In total, each oxygen atom has 8 electrons assigned to it.Now, we can calculate the formal charge for each atom:Formal charge of S = Valence electrons - Assigned electrons = 6 - 12 = -6Formal charge of O  resonance structure  = Valence electrons - Assigned electrons = 6 - 8 = -2Since there are three oxygen atoms, we need to divide the formal charge of sulfur by 3 to distribute it equally among the oxygen atoms:Formal charge of S  resonance structure  = -6 / 3 = -2Now, the formal charges are:Sulfur: -2Oxygen  x3 : -2The sum of the formal charges is -8, which is still not equal to the overall charge of the molecule. This indicates that there is an error in the calculation or the molecule's description. In fact, the molecule should be SO3^2-, which is the sulfite ion, not a neutral molecule.Considering the sulfite ion  SO3^2- , the formal charges are:Sulfur: +4Oxygen  x3 : -2The sum of the formal charges is now +4 +  -2  +  -2  +  -2  = -2, which matches the overall charge of the sulfite ion  SO3^2- .
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