The fourth member of the alkane series is butane. The molecular formula for butane is C4H10.The structural formula for butane is:CH3-CH2-CH2-CH3There are two possible isomers for butane:1. n-Butane normal butane : This is the straight-chain isomer, which has the structural formula mentioned above.2. Isobutane methylpropane : This is the branched isomer, with the structural formula:CH3 |CH3-C-CH3 | HSo, there are 2 possible isomers for the fourth member of the alkane series, butane.