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answer
27
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What is the mechanism for the preparation of 4-bromoacetanilide from acetanilide and bromine, and how does the mechanism differ from the preparation of aniline from nitrobenzene?
answered
Feb 22
in
Chemical synthesis
1
answer
21
views
What is the stepwise chemical reaction mechanism involved in the preparation of 2,4,6-trinitrotoluene from toluene and nitric acid, and what are the conditions required for each step?
asked
Feb 22
in
Chemical synthesis
1
answer
30
views
How does the photochemical properties of the active layer in photovoltaic cells affect the efficiency of the cell's conversion of sunlight to electrical energy?
answered
Feb 22
in
PhotoChemistry
1
answer
29
views
How does the photochemical property of phosphorescent materials affect their efficiency in converting light energy to chemical energy?
answered
Feb 22
in
PhotoChemistry
1
answer
25
views
What is the effect of increasing solvent polarity on the rate of the photochemical reaction of benzophenone in different solvents, such as ethanol, water, and acetone?
asked
Feb 19
in
PhotoChemistry
1
answer
27
views
What is the coordination number and structure for the complex [UO2(C2O4)(H2O)2]2-? How does the size of the ligands affect the coordination number and structure of the complex for lanthanide and actinide ions?
answered
Feb 19
in
Coordination Chemistry
1
answer
37
views
How does the coordination chemistry of lanthanide and actinide complexes differ from that of other transition metals?
asked
Feb 19
in
Coordination Chemistry
1
answer
113
views
What factors affect the rate of ligand substitution reactions in coordination chemistry? How do these factors influence the reaction mechanism and the overall outcome of the reaction? Provide a detailed explanation with specific examples.
answered
Feb 13
in
Coordination Chemistry
1
answer
90
views
What is the rate constant for the conversion of cyclopropane to propene if it follows first-order kinetics and has a rate of 4.67 x 10^-4 s^-1 at 25°C?
answered
Feb 13
in
Chemical kinetics
1
answer
61
views
What is the effect of chirality on the photochemical properties of molecules and how does it impact the formation of enantiomers? Provide a detailed explanation with relevant examples.
asked
Feb 12
in
PhotoChemistry
1
answer
39
views
How can the adhesion properties of a polymer be improved to enhance its bonding to specific surfaces, such as metals or glass, for industrial applications?
answered
Feb 6
in
Polymer Chemistry
1
answer
40
views
Calculate the standard enthalpy change for the sublimation of iodine (I2) if 1 mole of I2(s) is converted to 1 mole of I2(g) at 25°C and 1 bar pressure. Given the following information:- The standard enthalpy of fusion of I2 is 15.4 kJ/mol- The standard enthalpy of vaporization of I2 is 41.3 kJ/mol- The standard entropy change for the sublimation of I2 is 62.4 J/mol K.
asked
Feb 3
in
Chemical thermodynamics
1
answer
91
views
Calculate the standard enthalpy change for the following reaction: 2H2(g) + O2(g) → 2H2O(l)Given the standard enthalpies of formation for H2O (l), H2 (g) and O2 (g) are -285.8 kJ/mol, 0 kJ/mol and 0 kJ/mol, respectively.
asked
Feb 3
in
Chemical thermodynamics
1
answer
101
views
What is the role of ATP synthase in the oxidative phosphorylation process of the citric acid cycle? How does it contribute to the production of ATP molecules in the cell?
asked
Jan 31
in
BioChemistry
1
answer
86
views
Calculate the number of electrons transferred when a solution containing 0.50 mol of HCl reacts with 0.50 mol of NaOH in a redox reaction.
answered
Jan 30
in
ElectroChemistry
1
answer
82
views
Calculate the enthalpy of vaporization of water given the following information: - The boiling point of water is 100°C- The specific heat capacity of liquid water is 4.18 J/g·°C- The specific heat capacity of steam is 1.84 J/g·°C- The heat of fusion of water is 40.7 kJ/mol - The molar mass of water is 18.015 g/mol- The heat capacity of the container is negligible- Assume that the vaporized water behaves ideally and has a constant heat capacity
asked
Jan 23
in
ThermoChemistry
1
answer
72
views
Calculate the enthalpy of adsorption of benzene vapor on silica gel at 25°C and a pressure of 2.0 atm, given that the mass of adsorbent used is 0.25 g and the adsorption capacity of silica gel for benzene at this temperature and pressure is 0.75 g/g.
asked
Jan 23
in
ThermoChemistry
1
answer
79
views
Calculate the enthalpy change (ΔH) for the dissolution of 10 grams of NaOH in 100 mL of water, given that the final temperature after mixing is 28°C and the initial temperature of water was 25°C. The specific heat capacity of water is 4.18 J/g°C. The molar mass of NaOH is 40.00 g/mol and the enthalpy of dissolution for NaOH is -44.51 kJ/mol.
answered
Jan 23
in
ThermoChemistry
1
answer
52
views
Calculate the corrosion potential of a silver metal in a solution containing 0.1 M silver nitrate and 1 M nitric acid given that the standard reduction potential of the Ag⁺/Ag couple is +0.80 V and the standard reduction potential of the NO₃⁻/NO₂⁻ couple is +0.96 V.
asked
Jan 23
in
ElectroChemistry
1
answer
72
views
Calculate the area per molecule occupied by a monolayer of n-octadecane molecules adsorbed at the air-water interface assuming a surface pressure of 20 mN/m. The molecular weight of n-octadecane is 284.54 g/mol and its molecular area in the liquid phase is 0.219 nm². Use the Langmuir adsorption isotherm equation to solve the problem.
answered
Jan 23
in
Surface Chemistry
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