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What factors determine the rate of ligand substitution reactions in coordination chemistry, and what are the mechanisms of these reactions?
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Feb 13
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Coordination Chemistry
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Using retrosynthetic analysis, outline a viable multi-step synthesis of ibuprofen from commercially available starting materials. Include appropriate reagents and conditions.
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How can we design and synthesize small molecule inhibitors that selectively target autoimmune disease-causing immune cells and suppress their activity without affecting healthy cells in the body?
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How can we optimize the release rate of a drug from a polymer-based drug delivery system?
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What is the effect of increasing the concentration of reactants on the reaction rate and equilibrium of a chemical reaction?
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What are the resonance structures of the molecule C6H5NO2 (nitrobenzene)?
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Chemical bonding
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What is the net energy yield (in ATP) of glycolysis and gluconeogenesis, and how does this value differ between the two pathways?
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BioChemistry
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What is the mechanism by which Nitration of Benzene occurs in organic chemistry, and what is the effect of varying the concentration of Nitric acid on the rate of reaction?
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Feb 13
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Organic Chemistry
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What factors affect the solubility of an ionic compound in water?
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Chemical bonding
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One problem for a chemistry student to solve related to polymer chemistry and physical properties could be: What effect does molecular weight have on the viscosity of a polymer solution, and how can this be measured experimentally?
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Physical Chemistry
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What are the important factors that influence the binding affinity and catalytic activity of metal ions in metalloenzymes and metalloproteins? Provide a detailed explanation with examples.
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Feb 13
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Coordination Chemistry
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What is the hybridization of the central atom in the following inorganic compound: NH4+ ?
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Inorganic Chemistry
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What are the different types of liquid crystals and how do their properties differ? How do the properties of liquid crystals make them useful in electronic displays and other technological applications?
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Physical Chemistry
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What is the effect of changing the concentration of one reactant on the rate of a first or zero order reaction, and how can this effect be determined experimentally using different techniques such as the initial rate method and integrated rate laws?
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Feb 13
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Chemical kinetics
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What is the role of metal ions in the structure and function of metalloenzymes and metalloproteins, and how does their coordination chemistry contribute to their catalytic activity?
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Feb 13
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Coordination Chemistry
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How can we improve the sensitivity of gas sensors by synthesizing and characterizing new materials with high surface area and optimal molecular recognition properties?
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Materials Chemistry
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How do different ligands affect the photochemical properties of metal complexes?
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How does metal substitution affect the optical properties of metalloporphyrins and metallophthalocyanines studied for potential application in photovoltaic devices?
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Feb 13
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Coordination Chemistry
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What type of bond exists between a carbon atom (C) and an oxygen atom (O) in a carbon dioxide (CO2) molecule?
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Feb 13
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Chemical bonding
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How can we use molecular modeling techniques to design new compounds that target specific skin diseases, such as psoriasis or eczema, and minimize potential side effects?
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Medicinal Chemistry
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