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Calculate the corrosion current density of an iron rod having a surface area of 15 cm², immersed in an acid solution (pH=3) with a temperature of 50°C. The concentration of iron ions (Fe²⁺) in the solution is 0.1 M, and the standard reduction potential of iron is -0.44 V. The Tafel slope obtained experimentally is 0.12 V/decade. Use the Tafel equation to calculate the corrosion current density (in A/cm²) of the iron rod.

asked Jan 23 in ElectroChemistry by ClaritaSifue (1.8k points)

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1 answer 109 views

A student needs to find the enthalpy of polymerization of ethylene from the enthalpies of combustion of ethylene gas (-1411 kJ/mol) and polyethylene (-5120 kJ/mol). Calculate the enthalpy change, in kJ/mol, for the polymerization of ethylene gas to form polyethylene.

asked Jan 22 in ThermoChemistry by TracieM73151 (2.5k points)

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1 answer 72 views

Calculate the enthalpy change of dissolving 5.00 g of NaOH in 100.0 g of water. The temperature of the resulting solution increases from 25.00°C to 31.50°C. The specific heat capacity of the resulting solution is 4.18 J/g°C.

asked Jan 23 in ThermoChemistry by EloisaPtm353 (1.9k points)

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1 answer 81 views

Calculate the activation energy and reaction rate constant for the formation of hydrogen gas from the reaction of molecular hydrogen with atomic hydrogen using quantum chemical calculations.

asked Jan 23 in Computational Chemistry by BarneyUyv133 (1.7k points)

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1 answer 79 views

Calculate the area per molecule occupied by a monolayer of n-octadecane molecules adsorbed at the air-water interface assuming a surface pressure of 20 mN/m. The molecular weight of n-octadecane is 284.54 g/mol and its molecular area in the liquid phase is 0.219 nm². Use the Langmuir adsorption isotherm equation to solve the problem.

asked Jan 23 in Surface Chemistry by ElmoMcColl39 (1.7k points)

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1 answer 73 views

Calculate the enthalpy change for the hydrolysis of 2 moles of sucrose (C12H22O11) into glucose (C6H12O6) and fructose (C6H12O6), given the enthalpy change of hydrolysis for glucose and fructose are -2801 and -2802 kJ/mol respectively.

asked Jan 23 in ThermoChemistry by BrianCherry (1.7k points)

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1 answer 71 views

Calculate the enthalpy of adsorption of hydrogen gas on platinum at 298 K, given that the maximum coverage of hydrogen on the platinum surface is 0.5 monolayers and the equilibrium constant for the process at 298 K is 2.5 x 10^3. Assume that the adsorption process is exothermic and that the standard enthalpy of formation of water is -286 kJ/mol.

asked Jan 23 in ThermoChemistry by YOKIva496594 (2.6k points)

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1 answer 113 views

A chemistry student wants to determine the surface area of a porous material using gas adsorption. The student has access to a BET specific surface area analyzer and pure nitrogen gas. What is the surface area of the porous material if the adsorption isotherm shows a monolayer formation at the partial pressure of nitrogen adsorption around 0.1?

asked Jan 22 in Surface Chemistry by ChloeBodnar (2.0k points)

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Calculate the change in Gibbs free energy for the electrochemical reaction, given the standard reduction potentials of the reactants and products:Cu2+ (aq) + 2e- → Cu (s)E° = +0.34 VFe2+ (aq) + 2e- → Fe (s)E° = -0.44 V

asked Jan 23 in ElectroChemistry by WilburnMcCor (1.8k points)

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1 answer 113 views

A chemistry student wants to determine the specific heat capacity of an unknown metal. The student performs a calorimetry experiment and records the following data: - 50 mL of water at 25°C was added to a calorimeter. - The initial temperature of the metal was 100°C. - The final temperature of the metal and water mixture was 30°C. - The mass of the metal was 100 grams.What is the specific heat capacity of the metal?

asked Jan 22 in ThermoChemistry by AustinL82055 (1.8k points)

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1 answer 77 views

Calculate the change in entropy of the system when 2 moles of ammonia react to form 3 moles of hydrogen gas and 1 mole of nitrogen gas. The reaction takes place at a constant temperature of 298 K and at a pressure of 1 atm. The molar entropy of each component in the reaction is given below:Ammonia: 192.5 J/K·molHydrogen gas: 130.6 J/K·molNitrogen gas: 191.6 J/K·mol

asked Jan 23 in Chemical thermodynamics by TinaKesler6 (1.9k points)

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1 answer 76 views

Calculate the efficiency of an electrochemical cell with a standard potential of +0.80 V if the cell potential under operating conditions is +0.60 V and the current passing through the cell is 2.5 A.

asked Jan 23 in ElectroChemistry by LouellaComo (1.5k points)

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1 answer 77 views

Calculate the change in entropy for the combustion of methane gas (CH4) at constant pressure and temperature of 298 K. The products of the reaction are carbon dioxide gas (CO2) and water vapor (H2O). The molar entropy of CH4, CO2 and H2O at 298 K are 186.3 J/K/mol, 213.7 J/K/mol, and 188.8 J/K/mol, respectively.

asked Jan 23 in Chemical thermodynamics by TaylaBromby8 (2.2k points)

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1 answer 71 views

Calculate the enthalpy of adsorption for a reaction where 2 moles of nitrogen gas (N2) are adsorbed on the surface of a solid at -100°C. Given that the partial pressure of N2 in the gas phase is 0.2 atm and the equilibrium constant for adsorption of N2 at this temperature is 2.5 x 10^3. Assume the adsorption is a reversible process and that the ideal gas law can be used to calculate partial pressures.

asked Jan 23 in ThermoChemistry by KraigFeldman (2.2k points)

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1 answer 78 views

Calculate the bond energy required to break all the C-H bonds in a mole of methane (CH4) gas.

asked Jan 23 in Chemical reactions by ShanaHarpole (1.5k points)

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1 answer 149 views

How many moles of sulfuric acid (H2SO4) are required to react completely with 5 moles of magnesium hydroxide (Mg(OH)2) to produce magnesium sulfate (MgSO4) and water (H2O)?

asked Jan 21 in Inorganic Chemistry by MaybellHoffm (2.2k points)

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1 answer 118 views

A chemistry student is asked to find the standard cell potential for the redox reaction: Mg(s) | Mg²⁺(aq, 0.1 M) || Cu²⁺(aq, 0.01 M) | Cu(s) Given that the standard potential for the reduction of Mg²⁺ is -2.37 V and for the reduction of Cu²⁺ is +0.34 V. The student should show how to calculate the cell potential and determine if the reaction will proceed spontaneously or not.

asked Jan 22 in ElectroChemistry by TrudiMarron (1.6k points)

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1 answer 72 views

Calculate the enthalpy change for the precipitation reaction between 50.0 mL of 0.150 M silver nitrate solution and excess sodium chloride solution if the temperature change was measured to be -5.47°C. The molar mass of AgNO3 is 169.87 g/mol, and the density of the silver nitrate solution is 1.05 g/mL. The reaction is as follows: AgNO3(aq) + NaCl(aq) -> AgCl(s) + NaNO3(aq).

asked Jan 23 in ThermoChemistry by AdelaideYwt4 (1.6k points)

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1 answer 65 views

Calculate the enthalpy of vaporization for water at 100 °C, given that the vapor pressure of water is 101.325 kPa and its molar volume is 18.07 L/mol at boiling point.

asked Jan 23 in ThermoChemistry by Murray05Y450 (1.9k points)

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1 answer 64 views

Calculate the entropy change for the combustion of methane (CH4) at 298 K and 1 atm pressure, given the standard molar entropies of CH4, H2O (g), and O2 (g) are 186.3 J/K/mol, 188.7 J/K/mol, and 205.0 J/K/mol, respectively. The balanced chemical equation for the reaction is:CH4 (g) + 2 O2 (g) -> CO2 (g) + 2 H2O (g)

asked Jan 23 in Chemical thermodynamics by BelenPickard (2.3k points)

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