To calculate the vibrational frequency of CO2 molecule, we can use the formula for the wavenumber in cm: = 1/where is the wavelength in centimeters.First, we need to convert the given wavelength from micrometers m to centimeters cm :4.24 m = 4.24 x 10 m = 4.24 x 10 cmNow, we can calculate the wavenumber : = 1/ 4.24 x 10 cm = 2358.49 cmSo, the vibrational frequency of CO2 molecule using infrared spectroscopy with a wavelength of 4.24 m is approximately 2358.49 cm.