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What is the corrosion rate of iron in a 0.1M HCl solution at 25°C, given that the corrosion potential of the iron electrode is -0.44V vs. SHE and the Tafel slopes for the anodic and cathodic reactions are 60mV/dec and 120mV/dec, respectively?

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To calculate the corrosion rate of iron in a 0.1M HCl solution, we need to determine the corrosion current density  i_corr  first, and then convert it to a corrosion rate. We will use the Tafel extrapolation method to determine the corrosion current density.The Tafel extrapolation method involves the anodic and cathodic Tafel slopes  a and c  and the corrosion potential  E_corr . The anodic and cathodic reactions can be represented by the following Tafel equations:E = E_corr + a * log i / i_corr  for the anodic reactionE = E_corr - c * log i / i_corr  for the cathodic reactionGiven values:E_corr = -0.44 V vs. SHEa = 60 mV/dec  0.06 V/dec c = 120 mV/dec  0.12 V/dec Since we are dealing with a 0.1M HCl solution, the cathodic reaction is the reduction of hydrogen ions:2H + 2e  HThe exchange current density  i0  for this reaction can be calculated using the following equation:i0 = 10^  E_corr - E0  /  a - c   Where E0 is the standard potential for the hydrogen electrode, which is 0 V vs. SHE.i0 = 10^  -0.44 - 0  /  0.06 -  -0.12    i0 = 10^-0.44 / 0.18 i0 = 10^-2.44 i0  3.63 x 10^-3  A/mNow we can determine the corrosion current density  i_corr  using the following equation:i_corr = i0 *  10^E_corr / a  - 1 i_corr = 3.63 x 10^-3  *  10^-0.44 / 0.06  - 1 i_corr  3.63 x 10^-3  *  10^-7.33  - 1 i_corr  3.63 x 10^-3  *  -0.999 i_corr  3.63 x 10^-6  A/mNow that we have the corrosion current density, we can calculate the corrosion rate  CR  using Faraday's law:CR =  i_corr * M * n  /  F *  Where:M = molar mass of iron  55.85 g/mol n = number of electrons involved in the reaction  2 for the reduction of hydrogen ions F = Faraday's constant  96,485 C/mol  = density of iron  7.87 g/cm CR =  3.63 x 10^-6  * 55.85 * 2  /  96,485 * 7.87 CR  0.0000082 g/cm/yearThe corrosion rate of iron in a 0.1M HCl solution at 25C is approximately 0.0000082 g/cm/year.

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