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How does the temperature affect the adsorption of gas molecules on activated charcoal?

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The temperature plays a significant role in the adsorption of gas molecules on activated charcoal. Adsorption is a surface phenomenon in which gas molecules are attracted and held on the surface of a solid material, such as activated charcoal. The process is influenced by various factors, including the temperature, pressure, and the nature of the gas and the adsorbent.In general, the adsorption of gas molecules on activated charcoal is an exothermic process, meaning it releases heat. As the temperature increases, the adsorption capacity of activated charcoal decreases. This is because higher temperatures provide more energy to the gas molecules, making it harder for them to be held by the attractive forces on the surface of the activated charcoal.According to the van't Hoff equation, the adsorption isotherm can be related to temperature:ln K  = -H/RT + Cwhere K is the adsorption equilibrium constant, H is the enthalpy change of adsorption, R is the gas constant, T is the temperature in Kelvin, and C is a constant.From this equation, it can be seen that as the temperature  T  increases, the value of ln K  decreases, indicating a decrease in the adsorption capacity of the activated charcoal.In practical applications, this temperature dependence can be utilized to control the adsorption and desorption of gas molecules on activated charcoal. For example, in gas purification processes, lower temperatures are used to enhance the adsorption of impurities on activated charcoal. Conversely, in the regeneration of spent activated charcoal, higher temperatures are applied to facilitate the desorption of the adsorbed gas molecules, allowing the activated charcoal to be reused.
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