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How does the reaction mechanism of a chemical reaction affect the rate of the reaction? Provide specific examples of reactions with different mechanisms and explain how they affect the rate of the reaction.

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The reaction mechanism of a chemical reaction refers to the step-by-step sequence of elementary reactions by which the overall chemical change occurs. The rate of a chemical reaction is influenced by the reaction mechanism because each elementary step has its own rate constant and activation energy. The slowest step in the mechanism, known as the rate-determining step, ultimately controls the overall rate of the reaction.Here are two examples of reactions with different mechanisms and how they affect the rate of the reaction:1. SN1  Substitution Nucleophilic Unimolecular  Reaction:In an SN1 reaction, the rate-determining step involves the formation of a carbocation intermediate. For example, the reaction of tert-butyl bromide with water to form tert-butanol and hydrobromic acid: CH3 3CBr + H2O   CH3 3COH + HBrThe mechanism for this reaction involves two steps:Step 1  rate-determining step :  CH3 3CBr   CH3 3C+ + Br-Step 2:  CH3 3C+ + H2O   CH3 3COH + H+The rate of this reaction depends on the concentration of the substrate  tert-butyl bromide  only, as the first step is the slowest. The overall rate equation is: Rate = k[ CH3 3CBr]2. SN2  Substitution Nucleophilic Bimolecular  Reaction:In an SN2 reaction, the rate-determining step involves a direct nucleophilic attack on the substrate. For example, the reaction of ethyl bromide with hydroxide ions to form ethanol and bromide ions:CH3CH2Br + OH-  CH3CH2OH + Br-The mechanism for this reaction involves a single concerted step:Step 1  rate-determining step : CH3CH2Br + OH-  CH3CH2OH + Br-The rate of this reaction depends on the concentration of both the substrate  ethyl bromide  and the nucleophile  hydroxide ions . The overall rate equation is: Rate = k[CH3CH2Br][OH-]In summary, the reaction mechanism affects the rate of a chemical reaction by determining the rate-determining step and the concentrations of the species involved in that step. In the SN1 example, the rate depends only on the substrate concentration, while in the SN2 example, the rate depends on both the substrate and nucleophile concentrations. Understanding the reaction mechanism allows chemists to predict and control the rate of a reaction, which is crucial in various applications, such as chemical synthesis and drug design.

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