The reaction between potassium iodate KIO3 and sodium bisulfite NaHSO3 is an example of a redox reaction, where iodate ions IO3- are reduced to iodide ions I- and bisulfite ions HSO3- are oxidized to sulfate ions SO4^2- . The overall reaction can be represented as:3HSO3- + 2IO3- 3SO4^2- + I2However, this reaction does not occur in a single step. It involves the formation of reaction intermediates, which are species that are formed and consumed during the reaction but do not appear in the overall balanced equation. The presence of reaction intermediates can affect the rate of the reaction, as they are involved in the elementary steps that make up the reaction mechanism.In the case of the reaction between potassium iodate and sodium bisulfite, one possible intermediate is iodine I2 , which can form a complex with iodide ions I- to produce triiodide ions I3- . This intermediate formation can be represented as:I2 + I- I3-The rate of the overall reaction depends on the rate of the elementary steps involving the reaction intermediates. To investigate and measure the effect of the intermediates on the overall reaction rate, you can use various experimental techniques, such as:1. Monitoring the concentration of reactants and products over time: By measuring the concentration of the reactants KIO3 and NaHSO3 and products I2 and SO4^2- at different time intervals, you can determine the rate of the reaction and observe how it changes as the intermediates are formed and consumed.2. Varying the initial concentrations of the reactants: By performing the reaction with different initial concentrations of KIO3 and NaHSO3, you can study the effect of these changes on the reaction rate and gain insight into the role of the intermediates in the reaction mechanism.3. Adding a known concentration of the intermediate: By adding a known concentration of the intermediate e.g., I2 or I3- to the reaction mixture, you can observe how the presence of the intermediate affects the reaction rate. This can provide information about the role of the intermediate in the reaction mechanism.4. Using spectroscopic techniques: Techniques such as UV-Vis spectroscopy can be used to monitor the formation and consumption of the intermediates during the reaction. By analyzing the absorbance spectra, you can determine the concentration of the intermediates and their effect on the reaction rate.5. Performing kinetic studies: By analyzing the reaction rate as a function of the concentrations of the reactants and intermediates, you can determine the rate law and the reaction order with respect to each species. This information can help you understand the role of the intermediates in the reaction mechanism and their effect on the overall reaction rate.