0 votes
16 views
ago in Quantum Chemistry by (139k points)
What is the rate constant and mechanism for the reaction between ethylene and hydrogen at 298 K and 1 atm pressure, and how does the rate change when the temperature is increased to 373 K?

1 Answer

0 votes
ago by (139k points)
The reaction between ethylene  C2H4  and hydrogen  H2  is a hydrogenation reaction, which is commonly catalyzed by a metal catalyst such as palladium or platinum. The mechanism for this reaction is a surface catalyzed reaction, where the ethylene and hydrogen molecules adsorb onto the catalyst surface, and then the hydrogen atoms are transferred to the ethylene molecule to form ethane  C2H6 .The rate constant for this reaction at 298 K and 1 atm pressure can be determined using the Arrhenius equation:k = Ae^-Ea/RT where k is the rate constant, A is the pre-exponential factor, Ea is the activation energy, R is the gas constant  8.314 J/molK , and T is the temperature in Kelvin.Unfortunately, without specific values for the pre-exponential factor  A  and activation energy  Ea  for this reaction, it is not possible to calculate the exact rate constant. These values can be obtained from experimental data or from the literature.However, we can still discuss how the rate would change when the temperature is increased to 373 K. According to the Arrhenius equation, as the temperature increases, the rate constant  k  will also increase. This is because the exponential term e^-Ea/RT  becomes larger as the temperature increases, leading to a higher rate constant and a faster reaction rate.In summary, the mechanism for the reaction between ethylene and hydrogen is a surface catalyzed reaction, and the rate constant will increase when the temperature is increased from 298 K to 373 K. To determine the exact rate constant values, you would need the pre-exponential factor and activation energy for this specific reaction.

Related questions

Welcome to Sarvan Science Q&A, where you can ask questions and receive answers from other members of the community.
...