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How does the presence of reaction intermediates affect the overall rate of the reaction?

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The presence of reaction intermediates can significantly affect the overall rate of a chemical reaction. Reaction intermediates are short-lived, high-energy species that are formed during the course of a reaction but are not present in the final products or reactants. They are typically involved in multi-step reactions, also known as reaction mechanisms.The overall rate of a reaction depends on the rate-determining step, which is the slowest step in the reaction mechanism. The presence of reaction intermediates can influence the rate-determining step in several ways:1. Stabilization of intermediates: If a reaction intermediate is stabilized by the surrounding environment  e.g., through hydrogen bonding or other intermolecular forces , it may lower the activation energy required for the subsequent reaction step. This can increase the rate of the reaction.2. Catalysis: Catalysts can speed up a reaction by providing an alternative reaction pathway with a lower activation energy. In some cases, catalysts can interact with reaction intermediates, forming new intermediates with lower activation energies. This can lead to a faster overall reaction rate.3. Reaction order: The presence of reaction intermediates can affect the reaction order, which is the relationship between the reaction rate and the concentrations of the reactants. In some cases, the formation of an intermediate can lead to a change in the reaction order, which can either increase or decrease the overall reaction rate.4. Reaction reversibility: In some cases, reaction intermediates can participate in reversible reactions, where they can be converted back into reactants. If the reverse reaction is faster than the forward reaction, it can slow down the overall reaction rate.In summary, the presence of reaction intermediates can affect the overall rate of a chemical reaction by influencing the rate-determining step, participating in catalysis, changing the reaction order, and affecting reaction reversibility. The specific impact on the reaction rate will depend on the nature of the intermediates and the reaction mechanism.
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