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How does the presence of reaction intermediates influence the rate of a chemical reaction? Provide experimental evidence to support your answer using a specific reaction and varying the concentration of the intermediate.

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The presence of reaction intermediates can influence the rate of a chemical reaction by affecting the overall reaction mechanism. Reaction intermediates are short-lived species that are formed and consumed during the reaction process. They can participate in multiple elementary steps, and their concentration can affect the rate of these steps, ultimately influencing the overall reaction rate.A classic example of a reaction involving an intermediate is the reaction between hydrogen and iodine to form hydrogen iodide:H2 + I2  2HIThis reaction proceeds through a two-step mechanism involving the formation of a reaction intermediate, the hydrogen iodide molecule  HI :Step 1: H2 + I2  HI + HI  slow Step 2: HI + HI  2HI  fast The overall reaction rate depends on the concentration of the intermediate HI. To provide experimental evidence for the influence of the intermediate on the reaction rate, we can perform a series of experiments by varying the initial concentration of HI and measuring the reaction rate.Experiment 1: [H2] = 1.0 M, [I2] = 1.0 M, [HI] = 0 MExperiment 2: [H2] = 1.0 M, [I2] = 1.0 M, [HI] = 0.5 MExperiment 3: [H2] = 1.0 M, [I2] = 1.0 M, [HI] = 1.0 MBy measuring the initial rate of the reaction in each experiment, we can observe the effect of varying the concentration of the intermediate HI. If the reaction rate increases with increasing HI concentration, this would provide evidence that the presence of the intermediate influences the reaction rate.The results of such experiments would likely show that the reaction rate increases with increasing HI concentration. This is because the presence of HI in the reaction mixture allows the second, faster step of the reaction to occur more readily, effectively increasing the overall reaction rate. This experimental evidence supports the idea that the presence of reaction intermediates can influence the rate of a chemical reaction.
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