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What is the optimal reaction conditions (temperature, pressure, time, and catalyst) required for the efficient synthesis of polyethylene terephthalate from terephthalic acid and ethylene glycol?

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The optimal reaction conditions for the efficient synthesis of polyethylene terephthalate  PET  from terephthalic acid and ethylene glycol are as follows:1. Temperature: The reaction typically occurs in two stages. In the first stage, esterification occurs at temperatures between 220-260C. In the second stage, polycondensation takes place at temperatures between 270-290C.2. Pressure: The first stage of the reaction  esterification  is carried out at atmospheric pressure. The second stage  polycondensation  is performed under reduced pressure, typically around 0.1-1.0 torr, to facilitate the removal of byproducts and promote polymerization.3. Time: The reaction time depends on the specific process and desired degree of polymerization. Generally, the esterification stage takes 1-2 hours, while the polycondensation stage can take anywhere from 2-6 hours.4. Catalyst: Common catalysts used for this reaction include antimony trioxide  Sb2O3 , titanium IV  isopropoxide  Ti OiPr 4 , and germanium dioxide  GeO2 . The catalyst is typically added in small amounts, around 100-300 ppm, to promote the reaction without causing unwanted side reactions or degradation of the polymer.These conditions may vary depending on the specific process and equipment used, but they provide a general guideline for the efficient synthesis of PET from terephthalic acid and ethylene glycol.

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