0 votes
22 views
ago in Organic Chemistry by (2.5k points)
What is the mechanism of the nucleophilic acyl substitution reaction between acetic anhydride and aniline?

1 Answer

0 votes
ago by (2.3k points)
The nucleophilic acyl substitution reaction between acetic anhydride  CH3CO 2O and aniline  C6H5NH2  involves the following steps:1. Nucleophilic attack: The nitrogen atom in the aniline molecule, which has a lone pair of electrons, acts as a nucleophile and attacks the electrophilic carbonyl carbon atom in the acetic anhydride molecule. This results in the formation of a tetrahedral intermediate and the breaking of the  bond between the carbonyl carbon and oxygen atoms.2. Proton transfer: The negatively charged oxygen atom in the tetrahedral intermediate abstracts a proton from the nitrogen atom in the aniline molecule, forming a new N-H bond and regenerating the carbonyl double bond  C=O .3. Leaving group departure: The negatively charged oxygen atom in the acetate ion  CH3COO-  acts as a leaving group, breaking the bond between the carbonyl carbon and the oxygen atom. This results in the formation of an acylated aniline molecule  C6H5NHC O CH3  and an acetate ion  CH3COO- .4. Acid-base reaction  optional : If the reaction is carried out in the presence of an acid, the acylated aniline molecule can undergo an acid-base reaction with the acid, resulting in the protonation of the nitrogen atom and the formation of a more stable ammonium salt.Overall, the reaction between acetic anhydride and aniline results in the formation of N-acetylaniline  C6H5NHC O CH3  and an acetate ion  CH3COO- . The mechanism is a classic example of a nucleophilic acyl substitution reaction, where the nucleophile  aniline  substitutes the leaving group  acetate ion  in the acyl compound  acetic anhydride .
Welcome to Sarvan Science Q&A, where you can ask questions and receive answers from other members of the community.
...