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What is the detailed mechanism of the electrophilic aromatic substitution reaction of nitration using nitric acid and sulfuric acid as the reagents on benzene?

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The electrophilic aromatic substitution reaction of nitration involves the addition of a nitro group  -NO2  to an aromatic ring, such as benzene. The reagents used in this reaction are nitric acid  HNO3  and sulfuric acid  H2SO4 . The detailed mechanism of this reaction can be described in the following steps:1. Generation of the electrophile  nitronium ion, NO2+ :The first step involves the formation of the electrophile, which is the nitronium ion  NO2+ . This is formed by the protonation of nitric acid  HNO3  by sulfuric acid  H2SO4 , followed by the loss of a water molecule  H2O .HNO3 + H2SO4  NO2+ + H3O+ + HSO4-2. Electrophilic attack on the aromatic ring:The electrophile, nitronium ion  NO2+ , attacks the aromatic ring  benzene  at one of its carbon atoms. This leads to the formation of a positively charged intermediate called a sigma complex or arenium ion. The aromaticity of the benzene ring is disrupted during this step.Benzene + NO2+  Sigma complex  arenium ion 3. Deprotonation and regeneration of aromaticity:In the final step, a proton  H+  is removed from the sigma complex by the bisulfate ion  HSO4-  that was formed in the first step. This restores the aromaticity of the benzene ring and results in the formation of the nitrobenzene product.Sigma complex + HSO4-  Nitrobenzene + H2SO4Overall, the reaction can be summarized as:Benzene + HNO3 + H2SO4  Nitrobenzene + H2O + H2SO4This mechanism describes the electrophilic aromatic substitution reaction of nitration using nitric acid and sulfuric acid as the reagents on benzene.
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