0 votes
21 views
ago in Surface Chemistry by (139k points)
What is the critical micelle concentration (CMC) of sodium dodecyl sulfate (SDS) in water at room temperature and how does it vary with salt concentration?

1 Answer

0 votes
ago by (750 points)
The critical micelle concentration  CMC  of sodium dodecyl sulfate  SDS  in water at room temperature  around 25C  is approximately 8 mM  millimolar  or 0.008 mol/L. The CMC is the concentration at which surfactant molecules, such as SDS, start to aggregate and form micelles in a solution.The CMC of SDS can be affected by the presence of salts in the solution. Generally, the addition of salts can decrease the CMC of SDS. This phenomenon is known as the "salting-out" effect. The presence of salts can shield the electrostatic repulsion between the negatively charged head groups of SDS molecules, making it easier for them to aggregate and form micelles.The extent to which the CMC of SDS is affected by salt concentration depends on the type and concentration of the salt. For example, the addition of sodium chloride  NaCl  to the SDS solution can significantly decrease the CMC. As the concentration of NaCl increases, the CMC of SDS decreases, but the relationship is not linear. The effect of other salts on the CMC of SDS may vary depending on the specific salt and its concentration.
Welcome to Sarvan Science Q&A, where you can ask questions and receive answers from other members of the community.
...