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What is the coordination geometry and symmetry of a complex formed by the reaction of europium (III) chloride and ethylenediaminetetraacetic acid (EDTA)? How does the coordination number and geometry change with pH?

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The complex formed by the reaction of europium  III  chloride  EuCl  and ethylenediaminetetraacetic acid  EDTA  is a chelate complex, where EDTA acts as a hexadentate ligand. In this complex, europium  III  ion  Eu  is the central metal ion, and EDTA coordinates to it through its four carboxylate oxygen atoms and two nitrogen atoms from the amine groups.The coordination geometry of this complex is octahedral, with a coordination number of 6. The symmetry of the complex is O_h, which is the point group for an octahedral complex.The coordination number and geometry of the Eu-EDTA complex do not change significantly with pH. However, the speciation of the complex can change with pH. At low pH, the protonated forms of EDTA  e.g., HY, HY  can predominate, while at high pH, the fully deprotonated form of EDTA  Y  is more common. The formation of the Eu-EDTA complex is favored at higher pH values, where the fully deprotonated form of EDTA can chelate the metal ion more effectively.

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