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How does the acidity of phenols differ from that of alcohols and what is the reason behind it? Provide a rationale for your answer.

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The acidity of phenols is generally higher than that of alcohols. This difference in acidity can be attributed to the difference in the stability of the conjugate base formed after the loss of a proton  H+  from the phenol or alcohol molecule.When a phenol molecule loses a proton, it forms a phenoxide ion. The negative charge on the oxygen atom in the phenoxide ion is delocalized over the aromatic ring through resonance, which stabilizes the phenoxide ion. The resonance structures involve the movement of the negative charge from the oxygen atom to the carbon atoms in the aromatic ring, creating a more stable conjugate base. This stabilization of the phenoxide ion makes it easier for phenols to lose a proton, thus making them more acidic.On the other hand, when an alcohol molecule loses a proton, it forms an alkoxide ion. In this case, the negative charge on the oxygen atom is not delocalized, as there is no resonance stabilization available. The negative charge remains localized on the oxygen atom, resulting in a less stable conjugate base. This makes it more difficult for alcohols to lose a proton, making them less acidic compared to phenols.In summary, the difference in acidity between phenols and alcohols can be attributed to the difference in the stability of their conjugate bases. Phenols have a more stable conjugate base due to resonance stabilization, which makes them more acidic than alcohols.
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