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What is the structural difference between ethanol and propanol as determined by nuclear magnetic resonance (NMR) spectroscopy?

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Nuclear Magnetic Resonance  NMR  spectroscopy is a powerful analytical technique used to determine the structure of organic compounds by analyzing the environment of hydrogen atoms  protons  within the molecule. In the case of ethanol and propanol, the structural difference can be determined by comparing their proton NMR spectra.Ethanol  C2H5OH  has the following structure:CH3-CH2-OHPropanol can exist in two isomeric forms: 1-propanol and 2-propanol.1-propanol  C3H7OH  has the following structure:CH3-CH2-CH2-OH2-propanol  C3H7OH  has the following structure:CH3-CHOH-CH3In the proton NMR spectra of these compounds, the hydrogen atoms in different chemical environments will give rise to distinct peaks  signals  with different chemical shifts  measured in ppm .Ethanol:1. The CH3 group  3 protons  will give a peak around 1.0-1.5 ppm  methyl group .2. The CH2 group  2 protons  will give a peak around 3.5-4.0 ppm  methylene group adjacent to the OH group .3. The OH group  1 proton  will give a broad peak around 2.5-5.0 ppm  hydroxyl group .1-Propanol:1. The terminal CH3 group  3 protons  will give a peak around 0.8-1.2 ppm  methyl group .2. The middle CH2 group  2 protons  will give a peak around 1.5-2.5 ppm  methylene group adjacent to the terminal CH2 group .3. The CH2 group adjacent to the OH group  2 protons  will give a peak around 3.5-4.0 ppm.4. The OH group  1 proton  will give a broad peak around 2.5-5.0 ppm  hydroxyl group .2-Propanol:1. The two equivalent CH3 groups  6 protons in total  will give a peak around 1.0-1.5 ppm  methyl groups .2. The CH group  1 proton  will give a peak around 3.5-4.5 ppm  methine group adjacent to the OH group .3. The OH group  1 proton  will give a broad peak around 2.5-5.0 ppm  hydroxyl group .By comparing the proton NMR spectra of ethanol, 1-propanol, and 2-propanol, the structural differences can be identified based on the number of peaks, their chemical shifts, and the integration  proportional to the number of protons  of each peak.

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