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What is the effect of increasing the pH of a solution containing iron(III) and cyanide ions on the formation of the iron(III)-cyanide complex ion?

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Increasing the pH of a solution containing iron III  and cyanide ions will favor the formation of the iron III -cyanide complex ion. This is because cyanide ions  CN-  act as a ligand and can form coordination complexes with metal ions, such as iron III  ions  Fe3+ . The formation of the iron III -cyanide complex ion can be represented by the following equilibrium reaction:Fe3+ + 6CN- <=> Fe CN 6^3-As the pH of the solution increases, the concentration of hydrogen ions  H+  decreases. Cyanide ions can react with hydrogen ions to form hydrogen cyanide  HCN , as shown in the following reaction:CN- + H+ <=> HCNWhen the pH increases, this reaction is shifted to the left, resulting in a higher concentration of cyanide ions  CN-  in the solution. The increased concentration of cyanide ions will then shift the equilibrium of the iron III -cyanide complex formation to the right, favoring the formation of the complex ion Fe CN 6^3-.

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