To calculate the equilibrium constant Kc for the reaction, we can use the expression:Kc = [NO2]^2 / [N2O4]At equilibrium, the concentration of N2O4 is 0.02 M and the concentration of NO2 is 0.08 M. Plugging these values into the expression, we get:Kc = 0.08 ^2 / 0.02 Kc = 0.0064 / 0.02Kc = 0.32Therefore, the equilibrium constant Kc for this reaction is 0.32.