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Calculate the standard enthalpy change of the oxidation of hydrogen gas (H2) to form water (H2O) at 298 K, given that the standard enthalpy of formation of water is -285.8 kJ/mol and the bond dissociation enthalpy of the H-H bond is 436 kJ/mol.

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ago by (430 points)
To calculate the standard enthalpy change of the oxidation of hydrogen gas  H2  to form water  H2O , we can use the following equation:H_reaction = H_products - H_reactantsThe reaction can be written as:H2  g  + 1/2 O2  g   H2O  l The standard enthalpy change of the reaction  H_reaction  is the difference between the standard enthalpy of formation of water  H_products  and the bond dissociation enthalpy of the H-H bond  H_reactants .H_products = -285.8 kJ/mol  standard enthalpy of formation of water Since the bond dissociation enthalpy of the H-H bond is given as 436 kJ/mol, we need to consider that the reaction involves breaking one mole of H-H bonds and forming two moles of O-H bonds. The standard enthalpy change for breaking one mole of O=O bonds is also needed. The bond dissociation enthalpy of the O=O bond is 498 kJ/mol. Since we only need half a mole of O2 for the reaction, we will use half of this value.H_reactants = 436 kJ/mol  H-H bond  + 1/2 * 498 kJ/mol  O=O bond  = 436 + 249 = 685 kJ/molNow, we can calculate the standard enthalpy change of the reaction:H_reaction = H_products - H_reactants = -285.8 kJ/mol - 685 kJ/mol = -970.8 kJ/molThe standard enthalpy change of the oxidation of hydrogen gas  H2  to form water  H2O  at 298 K is -970.8 kJ/mol.

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