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How can acetanilide be converted into 4-bromoacetanilide using bromine as a reagent, and what would be the mechanism of this chemical synthesis reaction?

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Acetanilide can be converted into 4-bromoacetanilide using bromine as a reagent through a process called electrophilic aromatic substitution. In this reaction, bromine acts as an electrophile, and acetanilide acts as a nucleophile. The mechanism of this chemical synthesis reaction involves the following steps:1. Formation of the electrophile: Bromine  Br2  reacts with a Lewis acid catalyst, such as aluminum bromide  AlBr3  or iron III  bromide  FeBr3 , to form a highly electrophilic bromonium ion  Br+ .   Br2 + AlBr3  Br+ + AlBr4-2. Attack of the nucleophile: The aromatic ring of acetanilide acts as a nucleophile and attacks the electrophilic bromonium ion  Br+ , forming a sigma complex  also known as an arenium ion . This step results in the temporary loss of aromaticity.3. Deprotonation: A base, which could be the AlBr4- or another molecule of acetanilide, abstracts a proton from the sigma complex, restoring the aromaticity of the ring and forming 4-bromoacetanilide.4. Regeneration of the catalyst: The Lewis acid catalyst is regenerated in the process, allowing it to be used again in the reaction.   HAlBr4-  AlBr3 + HBrOverall, the reaction can be represented as:   Acetanilide + Br2  4-Bromoacetanilide + HBrIt is important to note that the amide functional group in acetanilide is a meta-directing group, meaning it directs the electrophilic substitution to the meta position. However, the reaction can still occur at the para position  4-bromoacetanilide  due to the steric hindrance at the ortho positions. To increase the selectivity for the para product, the reaction can be carried out at low temperatures and with a slight excess of bromine.

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