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ago in Chemical kinetics by (390 points)
How does changing the pressure of the reactants in a chemical reaction affect the rate of reaction, according to the collision theory?

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ago by (610 points)
According to the collision theory, the rate of a chemical reaction depends on the frequency of collisions between reactant molecules and the fraction of collisions that have sufficient energy and proper orientation to result in a successful reaction. When the pressure of the reactants in a chemical reaction is increased, the concentration of the reactants also increases  assuming constant temperature and volume . This means that there are more reactant molecules in the same volume, leading to a higher probability of collisions between the molecules. As a result, the frequency of collisions between reactant molecules increases.When the frequency of collisions increases, the chances of successful collisions with the proper orientation and sufficient energy also increase. Consequently, the rate of the reaction increases as well.In summary, increasing the pressure of the reactants in a chemical reaction generally leads to an increase in the rate of the reaction, according to the collision theory. This is because the increased pressure results in a higher concentration of reactants, leading to more frequent collisions and a higher probability of successful reactions.
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