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Calculate the enthalpy change when 2 moles of nitrogen gas are adsorbed onto the surface of activated charcoal at a temperature of 298 K, given that the pressure of nitrogen is 1 atm and the final pressure of nitrogen adsorbed is 0.5 atm. The standard enthalpy of formation of nitrogen gas is 0 kJ/mol.

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To calculate the enthalpy change for the adsorption of nitrogen gas onto activated charcoal, we can use the Clausius-Clapeyron equation, which relates the change in pressure to the change in enthalpy and temperature. The equation is as follows:ln P2/P1  = -H/R *  1/T2 - 1/T1 In this case, we have the initial pressure  P1  as 1 atm, the final pressure  P2  as 0.5 atm, and the temperature  T1 and T2  as 298 K. The gas constant  R  is 8.314 J/mol*K. Since the process occurs at constant temperature, T1 = T2, and the equation simplifies to:ln P2/P1  = -H/R *  1/T - 1/T ln 0.5  = -H /  8.314 J/mol*K Now, we can solve for H:H = -8.314 J/mol*K * ln 0.5 H  5774 J/molSince we have 2 moles of nitrogen gas, the total enthalpy change for the adsorption process is:Total H = 2 * 5774 J/molTotal H  11548 JTherefore, the enthalpy change when 2 moles of nitrogen gas are adsorbed onto the surface of activated charcoal at a temperature of 298 K is approximately 11.548 kJ.

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