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Calculate the corrosion potential of iron (Fe) in a 0.1 M HCl solution at 25°C, given that the standard electrode potential for the Fe2+/Fe redox couple is -0.44 V and the standard hydrogen electrode potential at the same temperature and pressure is 0 V. What is the likelihood of iron corrosion in this environment?

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To calculate the corrosion potential of iron in a 0.1 M HCl solution, we can use the Nernst equation. The Nernst equation relates the reduction potential of a half-cell at any point in time to the standard electrode potential, temperature, and the activities of the chemical species involved in the redox reaction.For the Fe2+/Fe redox couple, the half-cell reaction is:Fe s   Fe2+ aq  + 2e-The Nernst equation for this redox couple is:E = E -  RT/nF  * ln Q where:E is the corrosion potentialE is the standard electrode potential  -0.44 V for Fe2+/Fe R is the gas constant  8.314 J/molK T is the temperature in Kelvin  25C = 298.15 K n is the number of electrons transferred in the half-cell reaction  2 for Fe2+/Fe F is the Faraday constant  96485 C/mol Q is the reaction quotient, which is equal to [Fe2+]/[Fe] for this reactionSince the iron is in its solid form, its activity is considered to be 1. In a 0.1 M HCl solution, the concentration of H+ ions is 0.1 M. The reaction between iron and H+ ions can be represented as:Fe s  + 2H+ aq   Fe2+ aq  + H2 g Assuming that the concentration of Fe2+ ions is negligible compared to the concentration of H+ ions, we can approximate the reaction quotient Q as:Q  [Fe2+]/[Fe]  [H+]/2  0.1/2 = 0.05Now we can plug the values into the Nernst equation:E = -0.44 -  8.314 * 298.15 /  2 * 96485   * ln 0.05 E  -0.44 -  -0.021  * ln 0.05 E  -0.44 + 0.060E  -0.38 VThe corrosion potential of iron in a 0.1 M HCl solution at 25C is approximately -0.38 V.Since the corrosion potential is more negative than the standard hydrogen electrode potential  0 V , there is a thermodynamic driving force for the iron to corrode in this environment. The likelihood of iron corrosion in this environment is high.

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