0 votes
50 views
in Inorganic Chemistry by (650 points)
Calculate the bond order and bond length of the carbon monoxide (CO) molecule. Show your work and state the type of bond formed between carbon and oxygen in CO.

1 Answer

0 votes
by (610 points)
To calculate the bond order of the carbon monoxide  CO  molecule, we need to consider its molecular orbital diagram. In the molecular orbital theory, bond order is defined as the difference between the number of bonding electrons and the number of antibonding electrons, divided by 2.Carbon has 6 electrons, and oxygen has 8 electrons. In CO, the 14 electrons are distributed in the molecular orbitals as follows:1.  1s  - 2 electrons  bonding 2. * 1s  - 2 electrons  antibonding 3.  2s  - 2 electrons  bonding 4. * 2s  - 2 electrons  antibonding 5.  2pz  - 2 electrons  bonding 6.  2px  and  2py  - 4 electrons  bonding 7. * 2px  and * 2py  - 0 electrons  antibonding Bond order =  Number of bonding electrons - Number of antibonding electrons  / 2Bond order =  10 - 4  / 2Bond order = 6 / 2Bond order = 3The bond order of the carbon monoxide  CO  molecule is 3, which means there is a triple bond between the carbon and oxygen atoms.Now, let's calculate the bond length. The bond length of a molecule is inversely proportional to the bond order. As the bond order increases, the bond length decreases. The experimental bond length of CO is 1.128   angstroms .The type of bond formed between carbon and oxygen in CO is a covalent bond, specifically a polar covalent bond. This is because the electronegativity difference between carbon  2.55  and oxygen  3.44  is 0.89, which falls in the range of 0.5 to 1.7 for polar covalent bonds. The oxygen atom is more electronegative, so it attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the carbon.

Related questions

Welcome to Sarvan Science Q&A, where you can ask questions and receive answers from other members of the community.
...