To solve this problem, we will use the balanced chemical equation for the reaction between calcium carbonate and hydrochloric acid, the molar mass of calcium carbonate, and the molar volume of a gas at STP.The balanced chemical equation for the reaction is:CaCO3 s + 2 HCl aq CaCl2 aq + H2O l + CO2 g First, we need to find the moles of calcium carbonate CaCO3 in 500 grams. The molar mass of CaCO3 is:Ca = 40.08 g/molC = 12.01 g/molO = 16.00 g/molMolar mass of CaCO3 = 40.08 + 12.01 + 3 16.00 = 100.09 g/molNow, we can find the moles of CaCO3:moles of CaCO3 = mass / molar mass = 500 g / 100.09 g/mol = 4.995 molesFrom the balanced chemical equation, we can see that 1 mole of CaCO3 produces 1 mole of CO2. Therefore, 4.995 moles of CaCO3 will produce 4.995 moles of CO2.At STP Standard Temperature and Pressure: 0C and 1 atm , 1 mole of any gas occupies 22.4 liters. So, we can find the volume of CO2 produced:Volume of CO2 = moles of CO2 molar volume at STP = 4.995 moles 22.4 L/mol = 111.89 LTherefore, the student can produce approximately 111.89 liters of carbon dioxide gas at STP.