To calculate the rate constant k for a first-order reaction, we can use the formula for the half-life of a first-order reaction:t½ = 0.693 / kwhere t½ is the half-life of the reaction and k is the rate constant.We are given the half-life t½ as 20 seconds, and we need to find the rate constant k . We can rearrange the formula to solve for k:k = 0.693 / t½Now, we can plug in the given half-life:k = 0.693 / 20 sk 0.03465 sThe rate constant k for the reaction is approximately 0.03465 s.