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A chemical engineer needs to design a distillation column for the separation of a mixture containing ethanol (boiling point of 78.4°C) and water. The desired composition of the distillate is a minimum of 90% ethanol. What is the minimum number of theoretical trays needed in the column to achieve this composition, given that the feed contains 40% ethanol and the reflux ratio is 1.5?

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To determine the minimum number of theoretical trays needed in the distillation column, we can use the Fenske-Underwood-Gilliland  FUG  method. This method involves three main steps: finding the minimum reflux ratio  Rm , finding the actual reflux ratio  R , and calculating the number of theoretical trays  N .1. Calculate the minimum reflux ratio  Rm  using the Underwood equation:Rm =   - 1  /   - xD/xW Where  is the relative volatility, xD is the mole fraction of ethanol in the distillate, and xW is the mole fraction of ethanol in the waste.Assuming a relative volatility    of 2.3 for ethanol and water, and the desired distillate composition of 90% ethanol  xD = 0.9 , we can calculate xW using the feed composition of 40% ethanol  xF = 0.4 :xF =  xD * D  /  xD * D + xW * W Assuming a basis of 100 mol feed, D + W = 100, and D = xD * 100 /  xD + xW xF =  xD * xD * 100  /  xD^2 * 100 + xW * xW * 100 0.4 =  0.9 * 0.9 * 100  /  0.9^2 * 100 + xW^2 * 100 Solving for xW, we get xW  0.1.Now, we can calculate the minimum reflux ratio  Rm :Rm =  2.3 - 1  /  2.3 - 0.9/0.1 Rm  1.132. Calculate the actual reflux ratio  R :Given that the reflux ratio is 1.5, R = 1.5.3. Calculate the number of theoretical trays  N  using the Gilliland correlation:N = [ R - Rm  /  R + 1 ]^0.5 *  Nmin - 1  + 1Where Nmin is the minimum number of theoretical trays, which can be estimated using the Fenske equation:Nmin = log[ xD *  1 - xF   /  xF *  1 - xD  ] / log  Nmin = log[ 0.9 *  1 - 0.4   /  0.4 *  1 - 0.9  ] / log 2.3 Nmin  3.5  rounding up to 4 Now, we can calculate the number of theoretical trays  N :N = [ 1.5 - 1.13  /  1.5 + 1 ]^0.5 *  4 - 1  + 1N  5.5  rounding up to 6 Therefore, the minimum number of theoretical trays needed in the distillation column to achieve the desired composition of 90% ethanol is 6.

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