0 votes
5 views
in Organic Chemistry by (550 points)
What is the mechanism for the reaction between benzene and HNO3 in the presence of H2SO4 to form nitrobenzene?

1 Answer

0 votes
by (470 points)
The reaction between benzene and HNO3 in the presence of H2SO4 to form nitrobenzene is an example of electrophilic aromatic substitution. The mechanism for this reaction can be described in the following steps:1. Generation of the electrophile: Nitric acid  HNO3  reacts with sulfuric acid  H2SO4  to form the nitronium ion  NO2+ , which is a strong electrophile.   HNO3 + H2SO4  NO2+ + HSO4- + H2O2. Electrophilic attack: The electrophile, NO2+, attacks the benzene ring, which is rich in electron density due to the delocalized  electrons. This results in the formation of a resonance-stabilized carbocation called the sigma complex or arenium ion.3. Deprotonation: A base, usually the bisulfate ion  HSO4-  formed in the first step, abstracts a proton from the sigma complex, restoring the aromaticity of the benzene ring and forming nitrobenzene as the final product.Overall, the reaction can be summarized as:Benzene + HNO3  in the presence of H2SO4   Nitrobenzene + H2O
Welcome to Sarvan Science Q&A, where you can ask questions and receive answers from other members of the community.
...