intrinsic magnetic field
We already know that the magnitude of angular momentum is quantized for electron orbits in atoms. The new insight is that the direction of the orbital angular momentum is also quantized. The fact that the orbital angular momentum can have only certain directions is called space quantization. Like many aspects of quantum mechanics, this quantization of direction is totally unexpected. On the macroscopic scale, orbital angular momentum, such as that of the moon around the earth, can have any magnitude and be in any direction. Detailed treatment of space quantization began to explain some complexities of atomic spectra, but certain patterns seemed to be caused by something else. As mentioned, spectral lines are actually closely spaced doublets, a characteristic called fine structure, as shown in Figure 30.53. The doublet changes when a magnetic field is applied, implying that whatever causes the doublet interacts with a magnetic field. In 1925, Sem Goudsmit and George Uhlenbeck, two Dutch physicists, successfully argued that electrons have properties analogous to a macroscopic charge spinning on its axis. Electrons, in fact, have an internal or intrinsic angular momentum called intrinsic spin S . Since electrons are charged, their intrinsic spin creates an intrinsic magnetic field.