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Calculate the extent of polarization for a cell in which a copper electrode is coupled with a silver electrode at 25°C. The copper electrode has a potential of -0.34 V and the silver electrode has a potential of 0.80 V. The initial concentration of copper ions and silver ions in the solution are 0.001 M and 0.01 M, respectively. The total resistance of the cell (including both the electrolyte and the external circuit) is 10 ohms. Assume that the transfer coefficient for both the copper and silver ions is 0.5, and the Faraday constant is 96,485 C/mol.

asked Jan 23 in ElectroChemistry by RogerDenning (2.4k points)

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Calculate the expected boiling point of lithium fluoride (LiF) using its experimental melting point and the heat of fusion, assuming it behaves ideally.

asked Jan 23 in Inorganic Chemistry by NataliaCaple (2.1k points)

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Calculate the exchange current density of a copper-copper(II) ion electrode at 25 °C, given that the standard potential of the electrode is +0.34 V versus the standard hydrogen electrode and the transfer coefficient of the electrode reaction is 0.5.

asked Jan 23 in ElectroChemistry by AlexK0785479 (1.8k points)

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Calculate the exchange current density for the redox reaction: Fe2+ + Cr2O72- + 14H+ → 2Fe3+ + 2Cr3+ + 7H2O Given that the standard potential for the reaction at 25°C is 1.33 V, the gas constant is 8.314 J/mol K, and the temperature is 298 K.

asked Jan 23 in ElectroChemistry by DarbyJackey7 (1.4k points)

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1 answer 63 views

Calculate the exchange current density for a Zinc electrode immersed in a solution containing 0.1 M Zinc ions at 25 degrees Celsius, given that the standard potential of the Zinc half-reaction is -0.76 V and the transfer coefficient is 0.5. (Assume concentration polarization effects to be negligible.)

asked Jan 23 in ElectroChemistry by KassieStarns (2.3k points)

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1 answer 47 views

Calculate the exchange current density for a zinc electrode immersed in a 1.0 M solution of zinc sulfate at 25°C when the overpotential is 0.05 V. The standard reduction potential for the Zn2+/Zn couple is -0.76 V. The transfer coefficient is 0.5. Assume that the concentration of the electrolyte does not change significantly during the reaction.

asked Jan 23 in ElectroChemistry by TroyWitcher8 (2.1k points)

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1 answer 82 views

Calculate the exchange current density for a redox reaction where the standard potential is 0.7 V, and the transfer coefficient is 0.5, given that the rate constant for the reaction is 5 × 10^-7 mol/cm^2*s.

asked Jan 23 in ElectroChemistry by AndrewSisley (2.1k points)

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1 answer 80 views

Calculate the exchange current density for a metal electrode immersed in a 1 M solution of its corresponding ions. The standard rate constant for the reaction is 6.3 x 10^-5 cm/s and the concentration of the electrons in the electrode is 5 x 10^23 atoms/cm^3. Additionally, assume the temperature is 25°C and the Faraday constant is 96,500 C/mol.

asked Jan 23 in ElectroChemistry by Leif76792351 (2.0k points)

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1 answer 69 views

Calculate the exchange current density at the interface between a silver electrode and an aqueous solution of silver ions, given that the standard reduction potential for the Ag+/Ag half-cell is +0.80 V, the concentration of Ag+ in the solution is 0.025 M, and the temperature is 25°C.

asked Jan 23 in ElectroChemistry by CornellNicho (2.1k points)

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Calculate the exchange current density at the cathode of a lithium-ion battery if the temperature of the battery is 25 °C, the standard potential of

asked Jan 23 in ElectroChemistry by OnitaLoftus1 (2.3k points)

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1 answer 70 views

Calculate the equilibrium constant, Kc, for the reaction:2SO2(g) + O2(g) ⇌ 2SO3(g) at a temperature of 600 K, given that the initial concentrations of SO2, O2, and SO3 were 0.025 M, 0.014 M, and 0 M, respectively, and at equilibrium [SO2] = 0.015 M, [O2] = 0.008 M, and [SO3] = 0.025 M.

asked Jan 23 in Chemical equilibrium by RandellBeggs (2.0k points)

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Calculate the equilibrium constant, Kc, for the reaction below at 25°C, if the concentration of CO2 is 0.10 M, the concentration of H2 is 0.20 M, and the concentration of CO is 0.30 M.CO2(g) + H2(g) ⇌ CO(g) + H2O(g)

asked Jan 23 in Physical Chemistry by MichelleHall (2.0k points)

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Calculate the equilibrium constant, Kc, for the reaction below at 25°C if the concentration of CO2 is 1.2 M, the concentration of H2 is 0.8 M and the concentration of CO is 0.6 M.CO2(g) + H2(g) ⇌ CO(g) + H2O(g)

asked Jan 23 in Chemical equilibrium by JanieCorso7 (1.9k points)

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Calculate the equilibrium constant, Kc, at 298 K for the reaction 2 SO2(g) + O2(g) ⇌ 2 SO3(g) when the initial concentrations of SO2, O2, and SO3 are 0.100 M, 0.200 M, and 0.300 M, respectively.

asked Jan 23 in Chemical equilibrium by HenryCharles (2.0k points)

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1 answer 85 views

Calculate the equilibrium constant, Ka, for the dissociation of a weak acid HA with an initial concentration of 0.10 M that ionizes to form H+ and A-. At equilibrium, the concentration of H+ is found to be 1.0 x 10^-5 M and the concentration of A- is 0.09 M.

asked Jan 23 in Chemical equilibrium by Sterling80B (2.1k points)

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1 answer 73 views

Calculate the equilibrium constant, K, for the electrochemical reaction below, given the standard reduction potentials at 298 K:2 H+ (aq) + 2 e- → H2 (g) E° = 0.00 VFe3+ (aq) + e- → Fe2+ (aq) E° = +0.771 V

asked Jan 23 in ElectroChemistry by TroyPurton77 (1.9k points)

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1 answer 67 views

Calculate the equilibrium constant for the reaction: 2 NOCl(g) ⇌ 2 NO(g) + Cl2(g) if at equilibrium the concentrations are [NOCl] = 0.050 M, [NO] = 0.030 M, and [Cl2] = 0.020 M.

asked Jan 23 in Chemical equilibrium by SNBBernd7967 (2.3k points)

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1 answer 82 views

Calculate the equilibrium constant for the reaction that occurs when a copper electrode is placed in a solution of 0.1 M copper(II) sulfate and connected to a standard hydrogen electrode. The cell potential at standard conditions is observed to be 0.34 V. (Hint: Use the Nernst equation to relate the cell potential to the equilibrium constant.)

asked Jan 23 in ElectroChemistry by YvetteLink0 (2.0k points)

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1 answer 85 views

Calculate the equilibrium constant for the reaction 2 SO2(g) + O2(g) ⇌ 2 SO3(g), given that the concentrations at equilibrium are [SO2] = 0.20 M, [O2] = 0.30 M and [SO3] = 0.50 M.

asked Jan 23 in Chemical equilibrium by ErickB565479 (1.8k points)

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Calculate the equilibrium constant for the following electrochemical reaction at a temperature of 25°C:$$\ce{Co^{2+} + 2e^- <=> Co(s)}$$Given that the standard reduction potential for the half-reaction is $-0.28\,\text{V}$ and the concentration of $\ce{Co^{2+}}$ is $0.1\,\text{M}$.

asked Jan 23 in ElectroChemistry by Shawn33B4717 (1.9k points)

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