lattice defect
Iron is oxidized to Fe2+ aq at an anodic site on the surface of the iron, which is often an impurity or a lattice defect. Oxygen is reduced to water at a different site on the surface of the iron, which acts as the cathode. Electrons are transferred from the anode to the cathode through the electrically conductive metal. Water is a solvent for the Fe2+ that is produced initially and acts as a salt bridge. Rust Fe2O3xH2O is formed by the subsequent oxidation of Fe2+ by atmospheric oxygen. In the corrosion process, iron metal acts as the anode in a galvanic cell and is oxidized to Fe2+; oxygen is reduced to water at the cathode. The relevant reactions are as follows:.
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