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Higher temperatures increase the rate of reaction in a lot of chemical reactions because they increase the frequency of what interaction between reactant particles?

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collisions

Raising the temperature of a chemical reaction usually results in a higher rate of reaction. When the reactant particles are heated, they move faster and faster. This results in a greater frequency of collisions. A more important effect of the temperature increase is that the collisions occur with a greater force and are thus more likely to surmount the activation energy barrier and go on to form products. Increasing the temperature of a reaction increases the number of effective collisions between reacting particles, so the reaction rate increases.

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