closer together
Particles of a hypothetical ideal gas have no significant volume and do not attract or repel each other. In general, real gases approximate this behavior at relatively low pressures and high temperatures. However, at high pressures, the molecules of a gas are crowded closer together, and the amount of empty space between the molecules is reduced. At these higher pressures, the volume of the gas molecules themselves becomes appreciable relative to the total volume occupied by the gas Figure 9.36 . The gas therefore becomes less compressible at these high pressures, and although its volume continues to decrease with increasing pressure, this decrease is not proportional as predicted by Boyles law.