redox reaction
a reductant or an oxidant; it is also a Lewis base. The other reactant Cl2 is an oxidant, so we expect a redox reaction to occur in which the carbon of CO is further oxidized. Because Cl2 is a two-electron oxidant and the carbon atom of CO can be oxidized by two electrons to the +4 oxidation state, the product is phosgene Cl2C=O . Unlike Cl2, BF3 is not a good oxidant, even though it contains boron in its highest oxidation state +3 . Nor can BF3 behave like a reductant. Like any other species with only six valence electrons, however, it is certainly a Lewis acid. Hence an acidbase reaction is the most likely alternative, especially because we know that CO can use the lone pair of electrons on carbon to act as a Lewis base. The most probable reaction is therefore the formation of a Lewis acidbase adduct. Typically, both reactants behave like reductants. Unless one of them can also behave like an oxidant, no reaction will occur. We know that Sr is an active metal because it lies far to the left in the periodic table and that it is more electropositive than carbon. Carbon is a nonmetal with a significantly higher electronegativity; it is therefore more likely to accept electrons in a redox reaction. We conclude, therefore, that Sr will be oxidized, and C will be reduced. Carbon forms ionic carbides with active metals, so the reaction will produce a species formally containing either C4 or C22. Those that contain C4 usually involve small, highly charged metal ions, so Sr2+ will produce the acetylide SrC2 instead. Exercise.