active metal
One way to keep iron from corroding is to keep it painted. The layer of paint prevents the water and oxygen necessary for rust formation from coming into contact with the iron. As long as the paint remains intact, the iron is protected from corrosion. Other strategies include alloying the iron with other metals. For example, stainless steel is mostly iron with a bit of chromium. The chromium tends to collect near the surface, where it forms an oxide layer that protects the iron. Zinc-plated or galvanized iron uses a different strategy. Zinc is more easily oxidized than iron because zinc has a lower reduction potential. Since zinc has a lower reduction potential, it is a more active metal. Thus, even if the zinc coating is scratched, the zinc will still oxidize before the iron. This suggests that this approach should work with other active metals. Another important way to protect metal is to make it the cathode in a galvanic cell. This is cathodic protection and can be used for metals other than just iron. For example, the rusting of underground iron storage tanks and pipes can be prevented or greatly reduced by connecting them to a more active metal such as zinc or magnesium Figure 17.18 . This is also used to protect the metal parts in water heaters. The more active metals lower reduction potential are called sacrificial anodes because as they get used up as they corrode oxidize at the anode. The metal being protected serves as the cathode, and so does not oxidize corrode . When the anodes are properly monitored and periodically replaced, the useful lifetime of the iron storage tank can be greatly extended.