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An organic compound was synthesized in the laboratory. The compound is known to contain three functional groups - an alcohol, an alkene, and an ester. Using IR spectroscopy, a broad peak was observed in the region between 3200-3400 cm^-1, which indicates the presence of the alcohol group. However, two different peaks were observed in the region between 1640-1680 cm^-1, which could correspond to either the alkene or ester group. Using other spectroscopic techniques such as NMR and mass spectrometry, determine the structure of the compound and identify which peak corresponds to the alkene or ester functional group.
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Jan 22
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Organic Chemistry
by
DonnellBeckh
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2.3k
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1
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51
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An industrial process involves the reaction of nitrogen gas and hydrogen gas to produce ammonia gas, in the presence of a catalyst. If the equilibrium constant for this reaction at a certain temperature is 6.2 × 10^-2 and the initial concentrations of nitrogen and hydrogen gases are 1.2 M and 0.8 M respectively, what would be the equilibrium concentrations of the reactants and products if the catalyst increases the rate of the forward reaction by a factor of 4?
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Jan 22
in
Chemical equilibrium
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BlancaVennin
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1
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An electrochemical cell has a standard emf of 1.10 V and a current of 0.500 A when operating at standard conditions. What is the power output of the cell?
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Jan 22
in
ElectroChemistry
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FinleySalern
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1.6k
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1
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58
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An aqueous solution of 1.0 M HCl is oxidized by a lead anode in a half-cell, while a half-cell with a hydrogen electrode is used as the standard reduction potential. If the electrode potential of the lead electrode is -0.13 V, what is the cell potential of the overall reaction?
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Jan 22
in
ElectroChemistry
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OrenTherrien
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1.8k
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0
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1
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32
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Ammonia and hydrochloric acid react to form ammonium chloride according to the equation: NH3(g) + HCl(g) ⇌ NH4Cl(s). If a student were to add 0.1 moles of NH4Cl to the mixture at equilibrium and the volume of the container is constant, what will be the new concentration of NH3(g) and HCl(g) in the mixture?
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Jan 22
in
Chemical equilibrium
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CaraPrerauer
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1
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48
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A zinc rod is being placed in a solution containing 0.1 M of copper (II) ions. Calculate the corrosion potential of the zinc rod in a galvanic couple with a standard hydrogen electrode at 25°C.
asked
Jan 22
in
ElectroChemistry
by
MorganMaguir
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2.0k
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0
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1
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62
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A zinc electrode was kept in a 0.1 M ZnSO4(aq) solution, and a copper electrode was kept in a 0.1 M CuSO4(aq) solution. When 1500 C of electricity was passed through the cell, how many grams of copper were deposited on the cathode? (Assume 100 % efficiency and the Faraday constant is 96500 C/mol)
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Jan 22
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ElectroChemistry
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AundreaWhitf
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A zinc electrode is immersed in a 1.0 M ZnSO4 solution and connected to a platinum electrode that is immersed in a 1.0 M CuSO4 solution. If the measured potential difference of the cell is 1.10 V at 25 °C, what is the polarization of the cell?
asked
Jan 22
in
ElectroChemistry
by
TraciCoomes1
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1.9k
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0
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1
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57
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A zinc electrode is connected to a copper electrode by a wire in a beaker that has a solution of 0.1 M CuSO4 and 0.1 M ZnSO4. The initial reduction potential of the copper electrode is +0.34 V, and the initial oxidation potential of zinc is –0.76 V. What is the potential difference between the two electrodes at 298 K, and what is the rate of the electrochemical reaction when the cell operates at a current of 2.50 A?
asked
Jan 22
in
ElectroChemistry
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OnaSchnell25
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1.8k
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0
votes
1
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12
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A voltaic cell consists of a standard hydrogen electrode and a copper electrode in a solution of copper(II) sulfate. The measured cell potential is 0.78 V at 25°C. If the concentration of copper(II) sulfate is 0.1 M, what is the resistance of the electrochemical cell?
asked
Jan 22
in
ElectroChemistry
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GlenSchramm
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1.7k
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0
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1
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58
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A student wishes to prepare a buffer solution by adding 0.20 moles of acetic acid (Ka = 1.8 x 10^-5) and 0.20 moles of sodium acetate in 1 liter of solution. The student adds 0.05 moles of hydrochloric acid (HCl) to the solution. Calculate the effect of adding the buffer on the equilibrium position of the acid-base reaction and determine the new pH of the solution.
asked
Jan 22
in
Chemical equilibrium
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ArleneLeichh
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2.1k
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1
answer
57
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A student wishes to determine the standard reduction potential of an unknown metal electrode in a half-cell. They set up an electrochemical cell using a known standard hydrogen electrode (SHE) as the reference electrode and the unknown metal electrode as the working electrode. A voltmeter is used to measure the potential difference between the two electrodes. The reading is +0.45 V. What is the standard reduction potential of the unknown metal electrode in volts?
asked
Jan 22
in
Physical Chemistry
by
BrentAshcrof
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1.5k
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0
votes
1
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61
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A student wishes to determine the power output of an electrochemical cell that utilizes a half-reaction of copper oxide reducing to copper and a half-reaction of zinc oxidizing to zinc ions. The initial concentrations of the copper and zinc ions in the cell are 1.00 M and 0.10 M, respectively. The cell operates for 60 minutes at a constant rate of 0.200 A. Given that the standard cell potential is 1.10 V, calculate the power output of the electrochemical cell.
asked
Jan 22
in
ElectroChemistry
by
AlfonsoJanze
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1.9k
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0
votes
1
answer
73
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A student wants to synthesize a polymer using the monomer vinyl chloride. The reaction is exothermic and produces a polymer with an average molecular weight of 50,000 g/mol. The enthalpy change of polymerization for this reaction is -121.8 kJ/mol. How much heat is liberated during the polymerization of 1 mol of vinyl chloride?
asked
Jan 22
in
ThermoChemistry
by
CorneliusChi
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1.6k
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0
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1
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56
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A student wants to produce aluminum oxide (Al2O3) in the lab. Write a balanced chemical equation for the reaction between aluminum and oxygen gas to form aluminum oxide. Calculate how many grams of Al2O3 can be produced from 25 grams of aluminum reacting with excess oxygen gas.
asked
Jan 22
in
Inorganic Chemistry
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ErnestineScr
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1.6k
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1
answer
71
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A student wants to prepare polyethylene using the radical polymerization process. The monomer used is ethylene, and the reaction occurs at a temperature of 60°C. The initiator used is benzoyl peroxide. The student wants to know the enthalpy change that occurs during the polymerization process. How can the student calculate the enthalpy of polymerization using the given information?
asked
Jan 22
in
ThermoChemistry
by
540252730007
(
1.9k
points)
0
votes
1
answer
102
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A student wants to measure the heat of crystallization of sodium acetate trihydrate. The student takes 50 g of sodium acetate trihydrate and dissolves it in 100 ml of water at 70°C. The solution is then allowed to cool to 20°C, during which the sodium acetate trihydrate crystallizes out. The student measures the temperature change during this process and finds that the temperature drops to 45°C. What is the heat of crystallization of sodium acetate trihydrate in kJ/mol?
asked
Jan 22
in
ThermoChemistry
by
CarrieMadiso
(
1.8k
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0
votes
1
answer
68
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A student wants to maximize the production of ammonia from nitrogen and hydrogen gases using the Haber process. Using Le Chatelier's principle, how can the reaction conditions be adjusted to increase the yield of ammonia? Specifically, how can changes in temperature, pressure, and concentration of reactants be used to increase the equilibrium concentration of ammonia?
asked
Jan 22
in
Chemical reactions
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HenryWalden
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1.6k
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69
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A student wants to know the equilibrium concentration of hydrogen gas and nitrogen gas at a particular temperature and pressure when they are mixed in a container in a 2:1 ratio. The student also wants to calculate the equilibrium constant of the reaction when nitrogen and hydrogen form ammonia. Can you help the student by designing a step-by-step procedure to find the equilibrium concentrations and equilibrium constant at the given conditions?
asked
Jan 22
in
Physical Chemistry
by
TaneshaDoss0
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1.9k
points)
0
votes
1
answer
61
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A student wants to know how the equilibrium position of a weak acid such as acetic acid would be affected if they add more acetate ion. If the initial concentration of acetic acid is 0.1 M and initial concentration of acetate ion is 0.05 M. What will be the new concentration of acetate ion necessary to increase the pH of the solution by 0.5 units?
asked
Jan 22
in
Chemical equilibrium
by
AgustinSteed
(
2.2k
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