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How does the coordination of metal ions within the active site of metalloenzymes and metalloproteins affect their reactivity and function? Provide specific examples of metalloproteins and identify the role of the metal ion in each.
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Feb 19
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Coordination Chemistry
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TimNakamura
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How does the degree of conjugation in a π-system affect the energy of the HOMO and LUMO orbitals of a molecule, and how can this information be obtained from quantum chemical calculations of excited states?
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Feb 19
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Computational Chemistry
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How effective are natural products in treating a specific disease compared to traditional medicinal compounds?
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What is the effect of changing the size and charge of the metal doping atoms on the reactivity and stability of Pt-doped graphene in the oxygen reduction reaction using density functional theory calculations?
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Computational Chemistry
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How does the dosage of specific existing medications affect their toxicity levels towards human cells?
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What is the effect of changing the pH on the equilibrium concentration of the complex ion Fe(CN)6 4- ? Provide a detailed explanation of the process involved in predicting the effect and the factors that influence the equilibrium.
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Feb 19
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Chemical equilibrium
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What is the mechanism behind the destructive impact of chlorofluorocarbons (CFCs) on the ozone layer, and how can this mechanism be leveraged to develop alternative compounds that do not harm the ozone layer?
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Feb 19
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Environmental Chemistry
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How does the degradation of polymers affect their stability and properties over time under different environmental conditions?
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Feb 19
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Polymer Chemistry
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How does the cooling rate affect the crystallinity and crystal morphology of a polymer?
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Feb 19
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Polymer Chemistry
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What is the effect of changing the incoming ligand on the rate of ligand substitution in a coordination complex? Provide experimental evidence to support your answer.
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Feb 19
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Coordination Chemistry
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How do the environmental conditions, such as temperature and UV light exposure, affect the degradation and stability of different types of polymers used in common household products?
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Feb 19
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Polymer Chemistry
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How does the coordination of metal ions in metalloenzymes and metalloproteins affect their catalytic activity? Provide specific examples and describe the mechanisms by which the coordination environment influences the enzymatic function.
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Feb 19
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Coordination Chemistry
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What is the effect of changing the concentration of reactants on the reaction rate and how does it differ for reactions with different mechanisms?
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Feb 19
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Chemical kinetics
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What is the effect of light on the electronic structure and reactivity of a specific molecule?
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Feb 19
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Quantum Chemistry
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How does the degree of polymerization affect the physical properties of polystyrene, specifically its melting point and glass transition temperature?
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Feb 19
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Physical Chemistry
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How does the deficiency of the enzyme phenylalanine hydroxylase affect the biosynthesis of amino acids in human metabolism, and what are the potential health consequences of this deficiency?
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Feb 19
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BioChemistry
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What is the effect of changing the concentration of reactants on the rate of a chemical reaction with different stoichiometries?
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Feb 19
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Chemical kinetics
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What is the dipole moment of the hydrogen chloride (HCl) molecule and why is the bond polar?
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Feb 19
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Chemical bonding
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What is the coordination number and geometry of the iron ion in the heme group of the myoglobin protein?
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Feb 19
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Coordination Chemistry
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What is the effect of temperature on the adsorption of a gas on a solid surface? Provide a detailed explanation of the process and factors that contribute to the temperature dependence of gas adsorption on a solid surface.
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Feb 19
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Physical Chemistry
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ChristalMahl
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