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Calculate the standard electrode potential for the following redox reaction at 298 K: Fe3+(aq) + e- → Fe2+(aq) Given that the standard electrode potential for the half-reaction Fe3+(aq) + e- → Fe2+(aq) is +0.77 V.

asked Feb 3 in Chemical thermodynamics by LaurenMacon (350 points)

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Calculate the standard Gibbs free energy change for the reaction that occurs when a cell consisting of a nickel electrode and a silver electrode is connected, given that the nickel electrode is immersed in a solution containing 0.010 M Ni2+ ions and the silver electrode is immersed in a solution containing 0.20 M Ag+ ions. The standard reduction potential for the Ni2+/Ni half-cell is -0.25 V and for the Ag+/Ag half-cell is +0.80 V.

asked Feb 3 in ElectroChemistry by CoraDown5757 (590 points)

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How does changing the reaction stoichiometry affect the rate of a chemical reaction between hydrogen peroxide and potassium iodide?

asked Feb 3 in Chemical kinetics by TammieDancy (570 points)

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Calculate the ΔHrxn for the combustion of methane gas (CH4) if the enthalpies of formation for methane, carbon dioxide, and water are -74.8, -393.5, and -285.8 kJ/mol respectively, using Hess's Law.

asked Feb 3 in Chemical reactions by DebRuffin757 (330 points)

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Design a chemical reactor for the production of 2000 kg of ammonia per hour from 3000 kg of nitrogen and 6000 kg of hydrogen per hour, using the Haber-Bosch process. Determine the most suitable operating conditions such as pressure, temperature, and catalyst type for maximum yield and cost-effectiveness.

asked Feb 3 in Chemical engineering by DwightSparro (590 points)

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Calculate the standard enthalpy change for the phase transition reaction of solid ammonium nitrate (NH4NO3) to gaseous NH3 and NO2, given that the standard enthalpy of formation for solid NH4NO3 is -365.5 kJ/mol, the standard enthalpy of formation for NH3(g) is -46.1 kJ/mol, and the standard enthalpy of formation for NO2(g) is 33.2 kJ/mol.

asked Feb 3 in Chemical thermodynamics by PatriceBuck (330 points)

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Consider the following chemical reaction: 2H2(g) + O2(g) ⇌ 2H2O(g)At a certain temperature and pressure, the partial pressures of H2, O2, and H2O are found to be 0.20 atm, 0.10 atm, and 0.80 atm, respectively. Calculate the reaction quotient (Qc) for this reaction at this temperature and pressure. Is the system at equilibrium? If not, in which direction will the reaction proceed to attain equilibrium?

asked Feb 3 in Chemical thermodynamics by KellyeWooler (470 points)

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Calculate the standard enthalpy change for the neutralization of 25 mL of 0.10 M hydrochloric acid with 25 mL of 0.10 M sodium hydroxide. Assume the specific heat capacity of the solution to be 4.18 J/(g*K) and the density of the solution to be 1.00 g/mL. The temperature change observed during the reaction was 4.5°C.

asked Feb 3 in Chemical thermodynamics by Maryellen94N (190 points)

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Calculate the reaction quotient, Q, for the following reaction at room temperature:$$\ce{CH4(g) + 2O2(g) -> CO2(g) + 2H2O(g)}$$Given:- Partial pressure of methane, $\ce{CH4}$ = 0.25 atm- Partial pressure of oxygen, $\ce{O2}$ = 0.75 atm- Partial pressure of carbon dioxide, $\ce{CO2}$ = 0.0 atm- Partial pressure of water vapor, $\ce{H2O(g)}$ = 0.0 atmUse Q to determine if the reaction is at equilibrium, or if it will shift towards the products or reactants to reach equilibrium.

asked Feb 3 in Chemical thermodynamics by WadeCiy8478 (530 points)

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Calculate the standard enthalpy of formation of glucose (C6H12O6) given that the standard enthalpies of combustion for glucose, carbon, and hydrogen are -2803.6 kJ/mol, -393.5 kJ/mol, and -285.8 kJ/mol, respectively.

asked Feb 3 in ThermoChemistry by JuneSantora (430 points)

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Design a chemical reactor with a capacity of 100 liters and determine the operating conditions (temperature, pressure, and flow rate) required to achieve a 95% yield of product X in a specific reaction. The reaction rate constant is known to be 0.1/min and the initial concentration of reactant A is 2 mol/L. Use the design equation for a first-order irreversible reaction and assume a constant density of the reaction mixture.

asked Feb 3 in Chemical engineering by DaleHayden7 (250 points)

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Calculate the standard enthalpy change for the reaction: 2Fe(s) + 3/2 O2(g) -> Fe2O3(s) given that the standard enthalpy of formation for Fe2O3(s) is -824.2 kJ/mol and that of Fe(s) is 0 kJ/mol.

asked Feb 3 in Chemical thermodynamics by JoleneNickel (450 points)

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Calculate the standard enthalpy change for the reaction where 3 moles of hydrogen gas react with 1 mole of nitrogen gas to form 2 moles of ammonia gas. Given the following thermochemical equation: N2(g) + 3 H2(g) → 2 NH3(g) ΔH° = −92.4 kJ/mol

asked Feb 3 in Chemical thermodynamics by JohnnyFeng5 (410 points)

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Design a chemical reactor for the exothermic reaction A + B -> C, given the following parameters: - The reaction takes place at a temperature of 500°C- The reaction rate constant is 0.05 L/mol/min- The feed stream contains both A and B in equal molar amounts, with a total flow rate of 100 L/min- The desired product, C, should have a concentration of at least 90% in the reactor effluent stream- The reactor should have a residence time of at least 5 minutes. Determine the type of reactor (batch, plug flow, or continuously-stirred tank) and the dimensions (volume, length, diameter) required to achieve the desired product concentration and residence time, assuming an isothermal and well-mixed reactor.

asked Feb 3 in Chemical engineering by Wendell4581 (330 points)

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How does changing the molecular weight of a polymer affect its melt viscosity and how can this be quantitatively measured using rheological measurements such as shear rate and shear stress?

asked Feb 3 in Polymer Chemistry by MirandaJephc (230 points)

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Calculate the surface area of a solid adsorbent material using BET theory, given that the mass of the adsorbent material is 2.5 g, the area occupied by each adsorbed layer is 15 Å², the number of monolayers formed is 4, and the value of the BET constant is 0.05.

asked Feb 3 in Surface Chemistry by LoriSelwyn3 (670 points)

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Calculate the standard enthalpy of formation of water using Hess's law and the following data:2H2(g) + O2(g) -> 2H2O(g) ΔH°rxn = -484 kJ/molH2(g) + 1/2O2(g) -> H2O(l) ΔH°rxn = -286 kJ/mol

asked Feb 3 in Chemical thermodynamics by Mandy1426166 (510 points)

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Calculate the standard enthalpy of formation of methane gas (CH4) given the following data:- ∆H°combustion of methane = -890.36 kJ/mol - ∆H°formation of H2O (l) = -285.8 kJ/mol - ∆H°formation of CO2 (g) = -393.5 kJ/mol

asked Feb 3 in ThermoChemistry by AliceCahill0 (390 points)

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Calculate the standard enthalpy change (in kJ/mol) for the dissolution of 3.50 g of potassium hydroxide (KOH) in 250.0 mL of water at 25°C, given that the molar heat of solution of KOH is -57.61 kJ/mol.

asked Feb 3 in Chemical thermodynamics by VanitaArregu (810 points)

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Calculate the standard Gibbs free energy change for the electrochemical reaction of zinc and copper ions: Zn(s) + Cu2+(aq) → Cu(s) + Zn2+(aq)Given the following standard electrode potentials: E°(Cu2+(aq) + 2e- → Cu(s)) = 0.34 V E°(Zn2+(aq) + 2e- → Zn(s)) = -0.76 V Assume standard conditions (25°C and 1 atm pressure) and that the concentrations of the copper and zinc ions are both 1 mol/L.

asked Feb 3 in ElectroChemistry by BrockTimmons (410 points)

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